In this Screen Tests interview, Chris Hemsworth confesses he blew his "Thor" audition then found out the producers wanted his brother Liam Hemsworth. When Natalie Portman wasn't available for her character Jane Foster's kiss scene with Thor, Chris nominated his wife Elsa Pataky to stand-in.

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Chris Hemsworth On Kissing His Wife in Thor and Losing Role To Liam | Screen Tests | W Magazine