Degree of hardness l EDTA for hardness l complexometric merhod l engineering chemistry l Dr. Avani
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 Published On Mar 14, 2023

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Today's topic include :Degrees of hardness and determination to hardness by EDTA method

Hardness of water

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EDTA (ethylene-diamine-tetraacetic acid) is a commonly used method for measuring the amount of hardness in water. The EDTA method works by chelating or binding to the calcium and magnesium ions present in the water, which allows them to be measured through a titration process.

Here are the basic steps involved in the EDTA method for measuring water hardness:

Collect a water sample and add a buffer solution to adjust the pH to around 10.

Add a few drops of indicator EBT is added in water solution. The color becomes wine red of solution as EBT forms unstable complexes with salts of cacium and magnesium.
now
Add titrate water solution with EDTA .The EDTA solution will bind to the calcium and magnesium ions in the water.
And when all salts react with EDTA then it will combine with salts of complex ( EBT- Ca +2)and EBT gets free at end point and color becomes black at end point


Slowly titrate a standard solution of a metal ion (usually zinc) into the water sample until the indicator changes color.

Calculate the hardness of the water sample in terms of calcium carbonate (CaCO3) equivalent, based on the amount of metal ion used in the titration.

The EDTA method is widely used because it is relatively simple, fast, and accurate. It can be used to measure total hardness (the sum of calcium and magnesium ions) or individual calcium and magnesium levels in water samples.
Dr. Avani pareek, Associate professor, JECRC

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